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Adsorption of Methylene Blue and Reactive Black 5 by Activated Carbon Derived from Tamarind Seeds

by Zaniah Ishak 1 , Sa’diah Salim 1 , Dilip Kumar 2
1 Faculty of Engineering, Universiti Teknologi Malaysia, Johor Bahru, Malaysia
2 Department of Civil Engineering, G B Pant Engg College, Pauri, Uttarakhand, India

SUBMITTED: 30 August 2021; ACCEPTED: 20 October 2021; PUBLISHED: 9 December 2021

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Abstract

Abstract

One of the most environmentally friendly methods to treat wastewater, especially synthetic dyes, is the production of activated carbon from agricultural waste. Tamarind seeds were transformed from negative-value waste into activated carbon in order to study the removal of synthetic dyes. The particular agro waste was soaked in ZnCl2 for chemical activation to increase its surface area and enhance its porosity. Physical activation of tamarind seeds was done by the carbonization process by burning at a temperature of 300 °C for 1 hour and cooling for 24 hours before washing with HCL to activate a pore surface for the tamarind seeds' carbon. The effects of parameters related to the adsorption of the dyes by tamarind seed activated carbon, such as contact time, initial concentration, absorbance dosage, and pH, were studied. The experimental data found that adsorption on both synthetic dyes exhibited a Langmuir isotherm in which the correlation value, R2, was 0.9227 (methylene blue) and 0.6117 (Reactive black 5). Meanwhile, the rate of adsorption for methylene blue (MB) and Reactive black 5 (RB5) by tamarind seed activated carbon was found to be well fitted in a pseudo-second-order model. More research is needed to meet the standard effluent of dyeing wastewater from the industrial sector.

Keywords: Synthetic dyes; activated carbon; tamarind seeds; adsorption; methylene blue; reactive black 5; isotherm model

Creative Commons Attribution 4.0 International (CC BY 4.0) License
© 2022 Zaniah Ishak, Sa’diah Salim, Dilip Kumar. This is an open access article distributed under the Creative Commons Attribution 4.0 International (CC BY 4.0) License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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Ishak, Z., Salim, S., & Kumar, D. (2021). Adsorption of Methylene Blue and Reactive Black 5 by Activated Carbon Derived from Tamarind Seeds. Tropical Aquatic and Soil Pollution, 2(1), 1–12. https://doi.org/10.53623/tasp.v2i1.26
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Carmen, Z.; Daniela, S. (2010). Textile Organic Dyes – Characteristics, Polluting Effects and Separation / Elimination Procedures from Industrial Effluents – A Critical Overview. Organic Pollutants Ten Years after the Stockholm Convention - Environmental and Analytical Update, 55–86. http://dx.doi.org/10.5772/32373.

Hadibarata, T.; Syafiuddin, A.; Al-Dhabaan, F.A.; Elshikh, M.S.; Rubiyatno (2018). Biodegradation of Mordant orange-1 using newly isolated strain Trichoderma harzianum RY44 and its metabolite appraisal. Bioprocess Biosystem Engineering, 41, 621–632. https://doi.org/10.1007/s00449-018-1897-0.

Singh, S.K.; Sharma, N.; Tiwari, D.P. (2012). Decolourisation of Synthetic Dyes by Agricultural Waste- A Review. International Journal of Scientific & Engineering Research. 3, 1-10. http://dx.doi.org/10.1515/9783110292855.1.

Uyguner-Demirel, C.S.; Bekbolet M. (2012) Green Chemistry for Green Treatment Technologies. In: Lofrano G. (eds) Emerging Compounds Removal from Wastewater. SpringerBriefs in Molecular Science. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-3916-1_1.

Sivakumar, B.; Kannan, C.; Karthikeyan, S. (2012). Preparation and characterization of activated carbon prepared from Balsamodendron Caudatum wood waste through various activation processes. Rasayan Journal Chemical, 5, 321-327.

Wang, Z., Xue, M., Huang, K., & Liu, Z. (2010). Textile Dyeing Wastewater Treatment, 91–116. https://doi.org/10.5772/22670.

Sudjaroen, Y.; Haubner, R.; Wurtele, G.; Hull, W.E.; Erben, G.; Spiegelhalder, B.; Owen, R.W. (2005). Isolation and structure elucidation of phenolic antioxidants from Tamarind (Tamarindus indica L.) seeds and pericarp. Food and Chemical Toxicology, 43, 1673-1682. http://dx.doi.org/10.1016/j.fct.2005.05.013.

Mohamad, M.Y.; Akram, H.B.; Bero, D.N. (2012). Tamarind Seed Extract Enhances Epidermal Wound Healing. International Journal of Biology, 4, 81-88. http://dx.doi.org/10.5539/ijb.v4n1p81.

Mopoung, S.; Moonsri, P.; Palas, W.; Khumpai, S. (2015). Characterization and Properties of Activated Carbon Prepared from Tamarind Seeds by KOH Activation for Fe(III) Adsorption from Aqueous Solution. The Scientific World Journal, 2015, 1-9. http://dx.doi.org/10.1155/2015/415961.

Patel, H.; Vashi, R.T. (2010). Adsorption of Crystal Violet Dye onto Tamarind Seed Powder. E-Journal of Chemistry, 7, 975-984. http://dx.doi.org/10.1155/2010/143439.

Priya, R.; Nithya, R.; Anuradha, R.; Kamachi, T. (2014). Removal of colour from crystal violet dye using low cost adsorbents. International Journal of ChemTech Research, 6, 4346-4351.

Kanawade, S.M.; Gaikwad, R.W. (2011). Removal of Methylene Blue from Effluent by Using Activated Carbon and Water Hyacinth as Adsorbent. International Journal of Chemical Engineering and Applications, 2, 317-319. http://dx.doi.org/10.7763/IJCEA.2011.V2.126.

Hai, F.I.; Yamamoto, K.; Fukushi, K. (2007). Hybrid treatment systems for dye wastewater. Critical Reviews in Environmental Science and Technology, 37, 315-377. http://dx.doi.org/10.1080/10643380601174723.

Mulugeta, M.; Lelisa, B. (2014). Removal of MethyleneBlue (Mb) dye from aqueous solution by bioadsorption onto untreated parthenium hystrophorous weed. Modern Chemistry & Applications. 2, 1-5.

Anuar, F.I.; Hadibarata, T.; Syafrudin, M.; Fona, Z. (2020). Removal of procion red MX-5B from aqueous solution by adsorption on Parkia speciosa (Stink bean) peel powder. Biointerface Research in Applied Chemistry, 10, 4774-4779. http://dx.doi.org/10.33263/BRIAC101.774779.

Dogan, M.; Ozdemir, Y.; Alkan, M. (2007). Adsorption kinetics and mechanism of cationic methyl violet and methylene blue dyes onto sepiolite. Dyes Pigments, 75, 701–713. http://dx.doi.org/10.1016/j.dyepig.2006.07.023.

Samadi, M.T.; Zolghadrnasab, H.; Godini, K.; Poormohammadi, A.; Ahmadian, M.; Shanesaz, S. (2015). Kinetic and adsorption studies of reactive black 5 removal using multi-walled carbon nanotubes from aqueous solution. Der Pharma Chemica, 7, 267-274.

Shaheed, M.A.; Hussein, F.H. (2014). Adsorption of Reactive Black 5 on Synthesized Titanium Dioxide Nanoparticles: Equilibrium Isotherm and Kinetic Studies. Journal of Nanomaterials, 1-11. http://dx.doi.org/10.1155/2014/198561.

Ramalakshmi, S.; Selvakumar, R.; Muthuchelian, K.; Swaminathan, K. (2011). Utilization of Modified Gloriosa superba Waste as an Adsorbent Utilization of Modified Gloriosa superba Waste as an Adsorbent. World Applied Sciences Journal, 15, 415-421.

Brahim, O.; Belmehdani, M.; Belgacem, A.; Hadoun, H.; Sadaoui, Z. (2014). Discoloration of Azo Dye Solutions by Adsorption on Activated Carbon Prepared from the Cryogenic Grinding of Used Tires. Chemical Engineering Transactions, 38, 121-126. http://dx.doi.org/10.3303/CET1438021.

Rahman, M.A.; Ruhul Amin, S.M.; Shafiqul Alam, A.M. (2012). Removal of Methylene Blue from Waste Water Using Activated Carbon Prepared from Rice Husk. Dhaka University Journal Science, 60, 185-189. http://dx.doi.org/10.3329/dujs.v60i2.11491.

Yousefi, N.; Fatehizadeh, A.; Azizi, E.; Ahmadian, M.; Ahmadi, A.; Rajabizadeh, A.; Toolabi, A. (2011). Adsorption of reactive black 5 dye onto modified wheat straw: isotherm and kinetics study. Sacha Journal of Environmental Studies. 1, 81-91.

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