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Article | Tropical Aquatic and Soil Pollution | Volume 4 - Issue 2 - 2024 | 127‒142 | https://doi.org/10.53623/tasp.v4i2.497
© 2024 by the author(s), and is licensed under the Creative Commons Attribution 4.0 International (CC BY 4.0) License Creative Commons Attribution 4.0 International (CC BY 4.0) License

Synthesis of Aluminum Oxide Nanoparticle Adsorbents from Waste Aluminum Foil and Assesses Their Efficiency in Removing Lead (II) Ions from Water

Author(s): Md Aktaruzzaman 1 , Sayed M.A. Salam 2 , M.G. Mostafa 1
Author(s) information:
1 Water Research Lab, Institute of Environmental Science, University of Rajshahi, Rajshahi 6205, Bangladesh
2 Department of Applied Chemistry and Chemical Engineering, University of Rajshahi, Rajshahi 6205, Bangladesh

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Tropical Aquatic and Soil Pollution

Volume 4 - Issue 2 - 2024

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Aluminum oxide nanoparticles have recently been applied to water treatment as adsorbents by researchers. In this study, aluminum oxide nanoparticles (AlONPs) were synthesized using scrap aluminum foil through a straightforward, inexpensive, and green approach, and their performance in adsorbing lead (II) ions from an aqueous solution was assessed. The synthesized nanoparticles were characterized using Fourier Transform Infrared Spectroscopy (FTIR), X-ray Diffraction (XRD), Transmission Electron Microscopy (TEM), and Scanning Electron Microscopy with Energy-Dispersive X-ray Spectroscopy (SEM-EDX) to analyze their bonding nature, particle size, phase composition, and surface morphology. They exhibited an average particle size of 32.73 nm, consisting predominantly of γ-Al2O3, with small amounts of α-Al2O3 and a minor unknown phase. The lead adsorption efficiency was evaluated under optimized parameters, including pH, contact time, and doses of both adsorbate and adsorbent. The results demonstrated that the AlONPs achieved a 98% removal efficiency within 30 minutes of contact time at a pH of 5.5. Additionally, the Freundlich adsorption isotherm model (R² value of 0.9972) and the pseudo-second-order kinetic model (qe) value of 37.97 mg/g) were shown to fit the lead adsorption process better than other models. Hence, the synthesized AlONPs offer potential as nanoparticle adsorbents for removing lead (II) ions from aqueous solutions.

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SUBMITTED: 16 September 2024
ACCEPTED: 24 October 2024
PUBLISHED: 13 November 2024
SUBMITTED to ACCEPTED: 38 days
DOI: https://doi.org/10.53623/tasp.v4i2.497

Cite this article
Aktaruzzaman, M. ., Salam, S. M. ., & Mostafa, M. . (2024). Synthesis of Aluminum Oxide Nanoparticle Adsorbents from Waste Aluminum Foil and Assesses Their Efficiency in Removing Lead (II) Ions from Water. Tropical Aquatic and Soil Pollution, 4(2), 127‒142. https://doi.org/10.53623/tasp.v4i2.497
Keywords
Adsorbent isotherms kinetics lead removal aluminum foil water treatment
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